Thor...

...just for the 'hammer" puns...

I used to own a comic book store and let me tell you there were of course a lot of joking about super heroes and sex but more about the female characters (I mean Wonder womans golden lasso was good for quite a few by itself)

The male characters never got talked about much because only 1 out of 20 customers were female and it does not seem like women fantasized about make believe characters the way that guys do. Personally I never have (although once at 14 I had this weird fetish for star fire from the teen titans maybe because she looked asian)

If I were to ever write a comic book based porn story it would have to be the Fantastic Four. Reed Richards could stretch any part of his body, his wife could create invisible projectile objects and turn invisible. Lets face it; there was some kinky shit going on in the Baxter Building.
 
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